Named Rearrangements and Reactions
A rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. Often a substituent moves from one atom to another atom in the same molecule. In the example below the substituent R moves from carbon atom 1 to carbon atom 2. A rearrangement is not well represented by simple and discrete electron transfers represented by curly arrows in organic chemistry texts. The actual mechanism of alkyl groups moving, as in Wagner-Meerwein rearrangement, probably involves transfer of the moving alkyl group fluidly along a bond, not ionic bond-breaking and forming. In pericyclic reactions, explanation by orbital interactions give a better picture than simple discrete electron transfers. It is, nevertheless, possible to draw the curved arrows for a sequence of discrete electron transfers that give the same result as a rearrangement reaction, although these are not necessarily realistic. In allylic rearrangement, the reaction is indeed ionic.
- Methods and Applications of Benzilic Acid Rearrangement
- Methods and Applications of Claisen Rearrangement and Condensation
- Methods and Applications of Cope Rearrangement, Kolbe-Schmitt Reaction
- Methods and Applications of Hofmann Elimination reactions
- Methods and Applications of Pinacol Rearrangement,and Meerwein-Ponndorf-Verley Reduction
- Methods and Applications of Suzuki Coupling reactions, Paal-Knorr Pyrrole Synthesis
- Methods and Applications of Wittig Rearrangement, Wurtz-Fittig Reaction
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