Organometallic Chemistry

Organometallic chemistry is the study of compounds containing at least one bond between a carbon atom of an organic compound and a metal, including alkaline, alkaline earth, transition metal, and other cases. Organometallic compounds are widely used both stoichiometrically in research and industrial chemical reactions, as well as in the role of catalysts to increase the rates of such reactions as in uses of homogeneous catalysis, where target molecules include polymers, pharmaceuticals, and many other types of practical products. Organometallic compounds are in which organic group are linked directly to the metal through at least one carbon atom. Compounds like Ti(OC4H9)4, Ca{N(CH3)2}2 and Fee(SC5H11)3 are therefore, not included in the list of organometallic compounds, although C6H5Ti(OC4H9)3 and (C5H5)2Zr(OOCCH3)2, would be organometallics. Organic group can be bound, is one way or the other, to almost all the elements in the periodic table and potentially therefore the number of organometallic compounds is almost unlimited. Based on organometallic catalysis in olefin polymerization a whole new technology was evolved. Nobel prizes for chemistry have been awarded to Zieglar and Natta (1963), Fischer and Willkinson(1973) for the discoveries in Organometallic chemistry and homogeneous catalysis.

 

  • Organometallic nomenclature
  • Carbonmetal Bonds in organometallic compounds
  • Grignard reagents
  • Transition metal organometallic compounds
  • Carbenes and carbenoids

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